Styrenation of air blown linseed oil via RAFT-mediated miniemulsion polymerization
Yazarlar (2)
Doç. Dr. Mesut YILMAZOĞLU Yalova Üniversitesi, Türkiye
A. Tuncer Erciyes
Istanbul Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Progress in Organic Coatings (Q1)
Dergi ISSN 0300-9440 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2018
Kabul Tarihi Yayınlanma Tarihi 01-01-2018
Cilt / Sayı / Sayfa 114 / 1 / 1–8 DOI 10.1016/j.porgcoat.2017.09.014
Makale Linki http://dx.doi.org/10.1016/j.porgcoat.2017.09.014
Özet
In this study styrenated oil products were prepared under miniemulsion conditions by reversible addition-fragmentation chain transfer polymerization (RAFT) technique using phenacyl morpholine dithiocarbamate (PMDC) as a RAFT agent. First, hydroperoxide groups were formed on the oil structure by air-blowing process. Then the prepared miniemulsion of air blown linseed oil (ABLO)-styrene mixture was subjected to styrenation in the presence of the RAFT agent. Miniemulsion was prepared by means of ultrasonication by using cetyl trimethyl ammonium bromide (CTAB) and hexadecane (HD) as surfactant and co-surfactant, respectively. The best miniemulsion conditions were determined by a new strategy based on the determination of the conditions ensuring not to change of droplet/particle size throughout the polymerization. In this way, the conditions for the elimination of monomer diffusion between droplets …
Anahtar Kelimeler
Binder | Miniemulsion | RAFT | Styrenated oil | Vegetable oil
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Google Scholar 7
Web of Science 6
Scopus 6
Styrenation of air blown linseed oil via RAFT-mediated miniemulsion polymerization

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