Improvement of cyclability of silicon containing carbon nanofiber anodes for lithium ion batteries by employing succinic anhydride as an electrolyte additive
    
Yazarlar (8)
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Solid State Electrochemistry
Dergi ISSN 1432-8488 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2013
Cilt / Sayı / Sayfa 17 / 5 / 1393–1399 DOI 10.1007/s10008-013-2005-7
Makale Linki http://link.springer.com/10.1007/s10008-013-2005-7
Özet
Si/C composite nanofibers were prepared by electrospinning and carbonization using polyacrylonitrile as the spinning medium and carbon precursor. The effect of electrolyte additive succinic anhydride (SA) on the electrochemical performance of Si/C composite nanofiber anodes was investigated. Results show that after 50 cycles, the discharge capacity of Si/C composite nanofiber anode with the SA-added electrolyte is 34 % higher than that with additive-free electrolyte. At 150th cycle, the capacity retention of Si/C composite nanofiber anode with SA-added electrolyte is 82 % under 70 % state-of-charge. It is demonstrated that adding additive SA in the electrolyte is an effective and economic way to improve the cyclability of high-capacity Si/C composite nanofibers for next-generation high-energy lithium-ion batteries.
Anahtar Kelimeler
Electrospinning | Carbon nanofiber | Si nanoparticle | Succinic anhydride | Lithium-ion batteries