Synthesis and characterization of xLi2MnO3 1-xLiMn1/3Ni1/3Co1/3O2 composite cathode materials for rechargeable lithium-ion batteries
    
Yazarlar (8)
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Power Sources
Dergi ISSN 0378-7753 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 11-2013
Cilt / Sayı / Sayfa 241 / 0 / 522–528 DOI 10.1016/j.jpowsour.2013.04.155
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0378775313007751
Özet
Various xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 (x = 0.1, 0.2, 0.3, 0.4, and 0.5) cathode materials were prepared by the one-step sol–gel route. The structure of xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 composites was determined by X-ray diffraction analysis. The surface morphology and microstructure of xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 composites were characterized using scanning electron microscopy and transmission electron microscopy. Electrochemical performance of xLi2MnO3·(1 − x)LiCo1/3Ni1/3Mn1/3O2 composites was evaluated in terms of capacity, cycling performance and rate capability. Although the morphology and structure were found to be affected by the Li2MnO3 content, all composites showed an α-NaFeO2 structure with R3m space group. Electrochemical results showed that cells using 0.3Li2MnO3·0.7LiCo1/3Ni1/3Mn1/3O2 composites had good performance, in terms of large …
Anahtar Kelimeler
Lithium-ion batteries | Cathodes | Electrochemical performance | Li-rich | xLi(2)MnO(3)center dot(1-x)LiCo1/3Ni1/3Mn1/3O2