Preparation and characterization of electrospun nanofiber coated membrane separators for lithium ion batteries
    
Yazarlar (6)
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Solid State Electrochemistry
Dergi ISSN 1432-8488 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 09-2014
Cilt / Sayı / Sayfa 18 / 9 / 2451–2458 DOI 10.1007/s10008-014-2501-4
Makale Linki http://link.springer.com/10.1007/s10008-014-2501-4
Özet
Nanofiber-coated membrane separators were prepared by electrospinning polyvinylidene fluoride-co-chlorotrifluoroethylene (PVDF-co-CTFE) nanofibers onto three different microporous membrane substrates. The nanofibers on the membrane substrates showed uniform morphology with average fiber diameters ranging from 129 to 134 nm. Electrolyte uptakes, ionic conductivities, and interfacial resistances were studied by soaking the nanofiber-coated membrane separators with a liquid electrolyte solution of 1 M lithium hexafluorophosphate in ethylene carbonate/dimethylcarbonate/ethylmethyl carbonate (1:1:1 by volume). Compared with uncoated membranes, nanofiber-coated membranes had greater electrolyte uptakes and lower interfacial resistances to the lithium electrode. It was also found that after soaking in the liquid electrolyte solution, nanofiber-coated membranes exhibited higher ionic conductivities …
Anahtar Kelimeler
Lithium-ion batteries | Polymer separators | Nanofibers | Electrospinning | PVDF-co-CTFE