Multifunctional and highly active zinc titanate incorporated with copper for adsorptive hot syngas desulfurization and photocatalytic dye degradation

TUNA, Özlem; Şimşek, Esra Bilgin; Durakçetin, Yeliz; Sarıoğlan, Alper

doi:10.1016/j.jtice.2020.04.008

Multifunctional and highly active zinc titanate incorporated with copper for adsorptive hot syngas desulfurization and photocatalytic dye degradation

Yazarlar (4)

Doç. Dr. Özlem TUNA Yalova Üniversitesi, Türkiye

Esra Bilgin Şimşek
Yalova Üniversitesi, Türkiye

Yeliz Durakçetin
Tubıtak Marmara Research Center, Türkiye

Alper Sarıoğlan
Tubıtak Marmara Research Center, Türkiye

Makale Türü	Özgün Makale
Makale Alt Türü	SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı	Journal of the Taiwan Institute of Chemical Engineers
Dergi ISSN	1876-1070 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI-Expanded
Dergi Grubu	Q1
Makale Dili	İngilizce
Basım Tarihi	07-2020
Cilt No	112
Sayı	1
Sayfalar	388 / 396
DOI Numarası	10.1016/j.jtice.2020.04.008
Makale Linki	http://dx.doi.org/10.1016/j.jtice.2020.04.008

Özet

Multifunctionality is of a paramount significance in the case of metal oxide-based material. In the present study, Cu-doped zinc titanates in different Cu/Zn weight ratios were prepared with co-precipitation method to utilize as an adsorbent and a photocatalysts for H2S removal and dye degradation, respectively. The structural and morphological analyses were carried out using XRD, XPS, SEM and BET. The experiment results showed that the catalysts had a desulfurization ability with the Cu/Zn weight ratio of 0.06:1, which H2S in the feed was captured with 100% efficiency in N2 atmosphere at 750 °C during 5 h, also the removal decreased to 57% in a reducing atmosphere at the end of 5 h. The appropriate Cu loading content could lead to the high active and low apparent activation energy. In addition, the Cu-based catalyst showed an excellent photocatalytic activity under UV light irradiation, which the degradation of Orange II (OII) was found to be 80% at the end of 3 h. The metal loading reduced the band-gap and increased oxygen vacancies of zinc titanate. The reactive adsorptive desulfurization and excellent photocatalytic activity results demonstrate Cu loaded zinc titanate as a promising material for multifunctional applications.

Anahtar Kelimeler

Adsorptive desulfurization | Orange II | Photocatalysis | Zinc titanate

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
SCOPUS	11

Multifunctional and highly active zinc titanate incorporated with copper for adsorptive hot syngas desulfurization and photocatalytic dye degradation

Dergi Adı	Journal of the Taiwan Institute of Chemical Engineers
Yayıncı	Taiwan Institute of Chemical Engineers
Açık Erişim	Hayır
ISSN	1876-1070
E-ISSN	1876-1089
CiteScore	10,8
SJR	0,982
SNIP	1,072

Multifunctional and highly active zinc titanate incorporated with copper for adsorptive hot syngas desulfurization and photocatalytic dye degradation

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