Investigation of boron adsorption by graphene oxide: equilibrium, kinetic, and thermodynamic studies
Yazarlar (5)
Mehmet Fatih Önen
İstanbul Teknik Üniversitesi, Türkiye
Doç. Dr. Nalan Erdöl Aydin İstanbul Teknik Üniversitesi, Türkiye
Dr. Öğr. Üyesi Osman Eksik Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Pelin BARAN Yalova Üniversitesi, Türkiye
Gülhayat Nasun Saygili
İstanbul Teknik Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Turkish Journal of Chemistry (Q3)
Dergi ISSN 1300-0527 Dergi Bilgileri (2023)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2023
Kabul Tarihi – Yayınlanma Tarihi 01-01-2023
Cilt / Sayı / Sayfa 47 / 3 / 656–666 DOI 10.55730/1300-0527.3568
Makale Linki http://dx.doi.org/10.55730/1300-0527.3568
UAK Araştırma Alanları
Ayırma İşlemleri
Özet
Graphene oxide, which has a great application in industry, is one of the promising carbonous materials. Modified Hummers method was applied to synthesize graphene oxide. Characterization techniques showed that pure graphene oxide was successfully obtained. Its adsorptive properties were investigated by boron adsorption. The results were demonstrated that boron adsorption on graphene oxide was a pH-dependent process and maximum adsorption was achieved at pH 6 (0.98 mg g–1). Langmuir adsorption capacity was calculated as 3.92 mg g–1 with R2= 0.99. The kinetic data brought to light that pseudosecond-order kinetic model was well described the experimental data (R2= 0.99), and according to thermodynamic parameters, boron adsorption has spontaneous and endothermic nature (ΔHo=15.47 kJ mol–1).
Anahtar Kelimeler
adsorption | boron | Graphene oxide | wastewater
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 3
Scopus 3
Investigation of boron adsorption by graphene oxide: equilibrium, kinetic, and thermodynamic studies