Synthesis and characterization of Zr(IV) doped immobilized cross-linked chitosan/perlite composite for acid orange II adsorption
Yazarlar (1)
Prof. Dr. Pelin BARAN Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı International Journal of Biological Macromolecules (Q1)
Dergi ISSN 0141-8130 Dergi Bilgileri (2018)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 10-2018
Kabul Tarihi – Yayınlanma Tarihi 01-10-2018
Cilt / Sayı / Sayfa 118 / 1 / 340–346 DOI 10.1016/j.ijbiomac.2018.06.065
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0141813017340291
UAK Araştırma Alanları
Ayırma İşlemleri
Özet
To enhance the adsorption capacity of chitosan for acid orange II (AOII) adsorption, a novel adsorbent, zirconium(IV) doped immobilized cross-linked chitosan/perlite (Zr(IV)-CS-PT) composite was synthesized and characterized. Batch studies were conducted to analyze the effect of different parameters on AOII adsorption, such as Zr (IV) loading amount, pH, adsorbent dosage and temperature. Also, kinetic data revealed that AOII adsorption was well described by pseudo-second order kinetic model. Langmuir adsorption isotherm model was best described the isotherm data and maximum adsorption capacity was found 476.2 mg/g at natural pH. The thermodynamic data showed that the AOII adsorption occurred spontaneously and endothermic nature. Desorption and recycle experiments showed that after six cycle the adsorption efficiency was decreased from 95.6% to 90.1%, which shows the Zr(IV)-CS-PT is a reusable, cost-effective and high adsorption capacity adsorbent.
Anahtar Kelimeler
Adsorption | Composite | Cross-linked chitosan | Orange II | Perlite | Zirconium