Synthesis and Structural Studies of Hydrazone Dioxime Ligand and Its Cu(II) and Ni(II) Complexes

ÖZCİMDER, Recep; Karaböcek, Serdar; Karaböcek, Nevin; Küçükdumlu, Aslıgül; Şenses, Esra

doi:10.1080/15533174.2011.591352

Synthesis and Structural Studies of Hydrazone Dioxime Ligand and Its Cu(II) and Ni(II) Complexes

Yazarlar (5)

Dr. Öğr. Üyesi Recep ÖZCİMDER Yalova Üniversitesi, Türkiye

Prof. Dr. Serdar Karaböcek Karadeniz Teknik Üniversitesi, Türkiye

Nevin Karaböcek
Karadeniz Teknik Üniversitesi, Türkiye

Aslıgül Küçükdumlu
Karadeniz Technical University, Türkiye

Esra Şenses
Karadeniz Technical University, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Synthesis and Reactivity in Inorganic Metal Organic and Nano Metal Chemistry (Q4)
Dergi ISSN	1553-3174 Dergi Bilgileri (2011)
Dergi Tarandığı Indeksler	SCI
Makale Dili	İngilizce	Basım Tarihi	10-2011
Kabul Tarihi	–	Yayınlanma Tarihi	01-10-2011
Cilt / Sayı / Sayfa	41 / 9 / 1095–1101	DOI	10.1080/15533174.2011.591352
Makale Linki	http://www.tandfonline.com/doi/abs/10.1080/15533174.2011.591352
UAK Araştırma Alanları	Fiziksel Kimya

Özet

A hydrazone oxime (H 2L) has been prepared in EtOH by reacting 2-hydrazine hydrate (2) with 2,3-butanedione monoxime (1). Homodinuclear copper(II), nickel(II), homotetranuclear copper( II), and heterotetranuclear copper(II)-nickel(II) complexes of H 2L have been prepared. The metal complexes have been characterized by elemental analyses, magnetic moments, infrared (IR), ultraviolet-visible (UV-vis), and mass and thermal analyses studies. The dinuclear copper(II) and nickel(II) complexes of H 2L were found to have a 1:1 metal:ligand ratio. In addition, total energy and heat formation for ligands (H 2L and DHyLH 2) by semiempirical PM3 calculations have shown that H 2L is more stable than DHyLH 2. Copyright © Taylor & Francis Group, LLC.

Anahtar Kelimeler

Dinuclear nickel(II) complex | Hydrazone dioxime | Tetranuclear copper(II) complex

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Scopus	6

Synthesis and Structural Studies of Hydrazone Dioxime Ligand and Its Cu(II) and Ni(II) Complexes

Dergi Adı	Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
Kısa Adı	SYNTH REACT INORG M
Yayıncı	TAYLOR & FRANCIS INC
Açık Erişim	Hayır
ISSN	1553-3174
E-ISSN	1553-3182
Wos Quartile	Q4
Tarandığı Indeksler	SCIE
WoS Kategoriler	CHEMISTRY, INORGANIC & NUCLEAR \| NANOSCIENCE & NANOTECHNOLOGY
Scopus Kategoriler