Synthesis of effective poly 4 vinylpyridine nanocomposites in situ polymerization from edges surfaces and interlayer galleries of clay
Yazarlar (4)
Prof. Dr. Sinan ŞEN Yalova Üniversitesi, Türkiye
Mine Memeşa
Nihan Nugay
Boğaziçi Üniversitesi, Türkiye
Turgut Nugay
Boğaziçi Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymer International
Dergi ISSN 0959-8103 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2006
Kabul Tarihi 01-09-2005 Yayınlanma Tarihi 05-12-2005
Cilt / Sayı / Sayfa 55 / 2 / 216–221 DOI 10.1002/pi.1944
Makale Linki http://doi.wiley.com/10.1002/pi.1944
UAK Araştırma Alanları
Polimer Bilimi ve Teknolojileri
Özet
AbstractPoly(4‐vinylpyridine) (P4VP) nanocomposites have been prepared by using an in situ polymerization method in the presence of organically modified montmorillonite (MMT) clays with a quarternary salt of cocoamine containing a vinyl group, as well as trimethoxy vinyl silane. The nanocomposites were characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). The desired exfoliated nanocomposite structure was achieved when the MMT modification was conducted in the presence of both modifiers, whereas individual modifications all resulted in intercalated structures. This resultant exfoliated nanocomposite was found to have better thermal stability and dynamic mechanical performance when compared to the other nanocomposites, even with 2 % clay loading. Copyright © 2005 Society of Chemical Industry
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