Properties and applications of nanoclay reinforced open-porous polymer composites
Yazarlar (5)
Elif Yüce
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
Prof. Dr. Sinan ŞEN Yalova Üniversitesi, Türkiye
Semih Saygı
Prof. Dr. Nevim San Yıldız Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Applied Polymer Science
Dergi ISSN 0021-8995 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 12-2017
Kabul Tarihi Yayınlanma Tarihi 26-07-2017
Cilt / Sayı / Sayfa 134 / 46 / 45522– DOI 10.1002/app.45522
Makale Linki http://doi.wiley.com/10.1002/app.45522
UAK Araştırma Alanları
Polimer Bilimi ve Teknolojileri
Özet
ABSTRACTOpen‐porous nanoclay reinforced polymer composites were prepared via high internal phase emulsion templating using 1,3‐butanediol dimethacrylate and surface modified montmorillonite (SM‐MMT). Organophilic clay was obtained by using a reactive intercalant—quaternary cocoamine salt having a styryl group—for surface modification of MMT. The clay modification resulted in not only intercalated silicate layers but also nanoclay particles compatible with the continuous phase of the emulsions. It was found that increasing clay amount leads to formation of hierarchical porous structure accompanied with larger cavities and interconnected pores. In this respect, cavity size of the resulting composites was found to be altered between 6.78 and 8.82 μm. On the other hand, as compared to bare composites, addition of clay particles increased compressive modulus of the resulting materials from 26.4 to 72.5 MPa. The adsorption capacities of the porous composites for methyl violet 2B were investigated by batch experiments and discussed as a function of their SM‐MMT loading. It was determined that, the dye adsorption of the composites increased with increasing nanoclay amount in the polymer matrix. Thus, the adsorption percentage of the composite loaded with 7 wt % nanoclay was found to be as high as 88%. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45522.
Anahtar Kelimeler
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Properties and applications of nanoclay reinforced open-porous polymer composites

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