Rubbery wound closure adhesives I design synthesis characterization and testing of polyisobutylene based cyanoacrylate homo and co networks
Yazarlar (5)
Istvan Szanka
College of Engineering And Polymer Science, Amerika Birleşik Devletleri
Amalia Szanka
College of Engineering And Polymer Science, Amerika Birleşik Devletleri
Prof. Dr. Sinan ŞEN Yalova Üniversitesi, Türkiye
Nihan Nugay
Boğaziçi Üniversitesi, Türkiye
Joseph P. Kennedy
College of Engineering And Polymer Science, Amerika Birleşik Devletleri
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Polymer Science Part A Polymer Chemistry (Q1)
Dergi ISSN 0887-624X Dergi Bilgileri (2015)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 07-2015
Kabul Tarihi – Yayınlanma Tarihi 28-03-2015
Cilt / Sayı / Sayfa 53 / 14 / 1640–1651 DOI 10.1002/pola.27606
Makale Linki http://doi.wiley.com/10.1002/pola.27606
UAK Araştırma Alanları
Polimer Bilimi ve Teknolojileri
Özet
Novel rubbery wound closures containing various proportions and molecular weights of polyisobutylene (PIB) and poly(2‐octyl cyanoacrylate) [P(OctCA)] for potential clinical use were designed, synthesized, characterized, and tested. Homo‐networks were prepared by crosslinking 3‐arm star‐shaped PIBs fitted with terminal cyanoacrylate groups, [Ø(PIB‐CA)3], and co‐networks by copolymerizing Ø(PIB‐CA)3 with OctCA using N‐dimethyl‐p‐toluidine (DMT). Neat Ø(PIB‐CA)3, and Ø(PIB‐CA)3/OctCA blends, upon contact with initiator, polymerize within seconds to optically transparent strong rubbery co‐networks, Ø(PIB‐CA)3‐co‐P(OctCA). Homo‐ and co‐network formation was demonstrated by sol/gel studies, and structures and properties were characterized by a battery of techniques. The Tg of P(OctCA) is 58 °C by DSC, and 75 °C by DMTA. Co‐networks comprising 25% Ø(PIB‐CA)3 (Mn = 2400 g/mol) and …
Anahtar Kelimeler
adhesives | cyanoacrylate | network | polyisobutylene | rubber | wound dressing