Tuning of Final Performances of Soybean Oil Based Polymer Nanocomposites Effect of Styryl Oil Functionalized Intercalant of Montmorillonite Reinforcer
Yazarlar (2)
Doç. Dr. Emre TEKAY Yalova Üniversitesi, Türkiye
Prof. Dr. Sinan ŞEN Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı International Polymer Processing (Q3)
Dergi ISSN 0930-777X Dergi Bilgileri (2015)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2015
Kabul Tarihi – Yayınlanma Tarihi 05-05-2015
Cilt / Sayı / Sayfa 30 / 2 / 248–255 DOI 10.3139/217.3006
Makale Linki http://www.hanser-elibrary.com/doi/10.3139/217.3006
UAK Araştırma Alanları
Polimer Bilimi ve Teknolojileri
Özet
Bio-based polymeric nanocomposites were prepared via polymerization of a monomer mixture of acrylated epoxidized soybean oil (AESO) and styrene in the presence of organophilic montmorillonite (MMT) clay by in-situ free-radical polymerization technique. MMT clay was rendered organophilic by a styryl/oil functionalized intercalant which is compatible with the two matrices and able to participate in the polymerization/crosslinking reaction. The presence of styryl group in the intercalant is also thought to be an original solution to the drawback mentioned in the literature arising from higher amount of small styrene monomer molecules in the clay galleries than larger AESO molecules at high clay loadings. The current design of the interclant is expected to allow polymer molecules grown from both AESO and styrene monomers inside the clay galleries and also from edges/surfaces of the silicate layers. In this study, a …
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