Synthesis of bio based polymeric nanocomposites from acrylated epoxidized soybean oil and montmorillonite clay in the presence of a bio based intercalant
Yazarlar (2)
Prof. Dr. Sinan ŞEN Yalova Üniversitesi, Türkiye
Gökhan Çaylı İstanbul Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymer International (Q2)
Dergi ISSN 0959-8103 Dergi Bilgileri (2010)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 08-2010
Kabul Tarihi 09-12-2009 Yayınlanma Tarihi 19-07-2010
Cilt / Sayı / Sayfa 59 / 8 / 1122–1129 DOI 10.1002/pi.2838
Makale Linki http://doi.wiley.com/10.1002/pi.2838
UAK Araştırma Alanları
Polimer Bilimi ve Teknolojileri
Özet
Polymeric nanocomposites were synthesized from functionalized soybean‐oil‐based polymer matrix and montmorillonite (MMT) clay using an in situ free radical polymerization reaction. Acrylated epoxidized soybean oil combined with styrene was used as the monomer. Organophilic MMT (OrgMMT) was obtained using a quaternized derivative of methyl oleate, which was synthesized from olive oil triglyceride, as a renewable intercalant. The resultant nanocomposites were characterized using X‐ray diffraction and atomic force microscopy. The effect of increased nanofiller loading on the thermal and mechanical properties of the nanocomposites was investigated using thermogravimetric analysis and dynamic mechanical analysis. It was found that the desired exfoliated nanocomposite structure was achieved when the OrgMMT loading was 1 and 2 wt%, whereas a partially exfoliated or intercalated nanocomposite …
Anahtar Kelimeler
Acrylated epoxidized soybean oil | Mechanical properties | Montmorillonite | Nanocomposite