Graphene-based copper oxide thin film nanostructures as high-efficiency photocathode for p-type dye-sensitized solar cells
     
Yazarlar (7)
Prof. Dr. Bayram KILIÇ Yalova Üniversitesi, Türkiye
Prof. Dr. Sunay TÜRKDOĞAN Yalova Üniversitesi, Türkiye
Aykut Astam Erzincan Üniversitesi, Türkiye
Sümeyra Seniha Baran Yalova Üniversitesi, Türkiye
Mansur Asgin Yalova Üniversitesi, Türkiye
Hülya Cebeci İstanbul Teknik Üniversitesi, Türkiye
Deniz Urk İstanbul Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Photonics for Energy
Dergi ISSN 1947-7988 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 10-2017
Cilt / Sayı / Sayfa 7 / 4 / 45502–0 DOI 10.1117/1.JPE.7.045502
Makale Linki https://www.spiedigitallibrary.org/journals/journal-of-photonics-for-energy/volume-7/issue-04/045502/Graphene-based-copper-oxide-thin-film-nanostructures-as-high-efficiency/10.1117/1.JPE.7.045502.full
Özet
Graphene-based p-type dye-sensitized solar cells (p-DSSCs) have been proposed and fabricated using copper oxide urchin-like nanostructures (COUN) as photocathode with an FeS2 counter electrode (CE). COUN composed of Cu2O core sphere and CuO shell nanorods with overall diameters of 2 to 4μm were grown by a simple hydrothermal method with self-assemble nucleation. It was figured out that the formation of copper oxide core/shell structures could be adjusted by an ammonia additive leading to pH change of the precursor solution. In addition to a photocathode, we also demonstrated FeS2 thin films as an efficient CE material alternative to the conventional Pt CEs in DSSCs. FeS2 nanostructures, with diameters of 50 to 80 nm, were synthesized by a similar hydrothermal approach. FeS2 nanostructures are demonstrated to be an outstanding CE material in p-DSSCs. We report graphene/COUN as photocathode and Pt/FeS2 as CE in p-DSSCs, and results show that the synergetic combination of electrodes in each side (increased interconnectivity between COUN and graphene layer, high surface area, and high catalytic activity of FeS2) increased the power conversion efficiency from 1.56% to 3.14%. The excellent performances of COUN and FeS2 thin film in working and CEs, respectively, make them unique choices among the various photocathode and CE materials studied.
Anahtar Kelimeler
graphene | CuO | Cu2O | p-DSSCs | pyrite (FeS2)
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
WoS 2
SCOPUS 4
Google Scholar 4
Graphene-based copper oxide thin film nanostructures as high-efficiency photocathode for p-type dye-sensitized solar cells

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İletişim
  • Yalova Üniversitesi Rektörlüğü, Bahçelievler Mah. Çınarcık Yolu Caddesi No: 26 Merkez - YALOVA, 77200
  • unis@yalova.edu.tr 0226 815 50 00
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