Polymeric organic Amberlite™ IRC-200 extract resin compound as a novel corrosion inhibitor for carbon steel in 1.0 M HCl acid: detail experimental, surface, molecular studies (DFT + MC/MD) and kinetic isotherm adsorption
    
Yazarlar (12)
Jaouad Bensalah Faculty Of Science, Ibn Tofail University, Fas
Abdelfettah Hmada Faculty Of Science, Ibn Tofail University, Fas
Said Bouzakraoui Faculty Of Science, Ibn Tofail University, Fas
Nadia Dkhireche Faculty Of Science, Ibn Tofail University, Fas
Abdelkader Zarrouk Faculté Des Sciences Rabat, Fas
Öğr. Gör. Dr. Şaban ERDOĞAN Yalova Üniversitesi, Türkiye
Burak Tüzün Cumhuriyet Üniversitesi, Türkiye
Nuha Wazzan Faculty Of Sciences, King Abdulaziz University, Suudi Arabistan
Zaki S. Safi Al-Azhar University Of Gaza, Filistin
Hamid Erramli Faculty Of Science, Ibn Tofail University, Fas
Mohamed Ebn Touhami Faculty Of Science, Ibn Tofail University, Fas
Amar Habsaoui Faculty Of Science, Ibn Tofail University, Fas
Makale Türü Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı Environmental Science and Pollution Research
Dergi ISSN 0944-1344 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SSCI
Makale Dili Türkçe Basım Tarihi 02-2025
Cilt / Sayı / Sayfa 32 / 9 / 5551–5573 DOI 10.1007/s11356-025-35884-9
Makale Linki https://doi.org/10.1007/s11356-025-35884-9
Özet
The potential adsorbent for inhibitors of corrosion in HCl 1.0 M was investigated using experimental and modeling data on a novel cationic polymeric resin composite called Amberlite™ IRC-200. The resin has a significantly better ability to adsorb the Ni(II) ions. Molecular dynamics (MD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and DFT theory were among the methods used to examine the polymeric adsorbent resin. In this work, the adsorbent cationic polymeric resin is used to suppress corrosion in HCl 1.0 M. Experimental results demonstrated that ACQ and DAQ significantly increased MS corrosion resistance; results from Tafel polarization demonstrated that resin polymeric compounds exhibited disordered-type inhibitory properties with varying corrosion rates. Results from the highest best impedance experiments showed that at 100 ppm, ACQ inhibited performance to a 94.9% degree. Adsorption of the cationic adsorbent polymeric resin followed the most recent findings in the Langmuir model, and the most recent estimations of thermodynamic parameters indicated physisorption. Scanning transmission electron microscopy was used to investigate the MS morphological investigation.
Anahtar Kelimeler
Adsorption resin | Amberlite™ IRC-200 polymeric | DFT/MC/MD | Mild steel corrosion | SEM/IR/EDS/XRD