Advanced evaluation of novel quinoline derivatives for corrosion inhibition of mild steel in acidic environments: A comprehensive electrochemical, computational, and surface study      
Yazarlar (11)
Azzeddine Belkheiri
Faculty Of Science, Ibn Tofail University, Fas
Khadija Dahmani
Faculty Of Science, Ibn Tofail University, Fas
Khaoula Mzioud
Faculty Of Science, Ibn Tofail University, Fas
Mohamed Rbaa
Faculty Of Science, Ibn Tofail University, Fas
Mouhsine Galai
Faculty Of Science, Ibn Tofail University, Fas
Abdelfettah Hmada
Faculty Of Science, Ibn Tofail University, Fas
Öğr. Gör. Şaban ERDOĞAN Yalova Üniversitesi, Türkiye
Burak Tüzün
Sivas Cumhuriyet Üniversitesi, Türkiye
Mohamed Ebn Touhami
Faculty Of Science, Ibn Tofail University, Fas
Hamed A. El-Serehy
College Of Sciences, Suudi Arabistan
Basheer M. Al-Maswari
Yuvarajas College, Hindistan
Makale Türü Açık Erişim Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı International Journal of Electrochemical Science
Dergi ISSN 1452-3981 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili Türkçe
Basım Tarihi 10-2024
Cilt No 19
Sayı 10
DOI Numarası 10.1016/j.ijoes.2024.100772
Makale Linki https://doi.org/10.1016/j.ijoes.2024.100772
Özet
Corrosion poses a significant threat to the integrity and longevity of iron and its alloys, which are crucial materials for modern industry and infrastructure. This study investigates the effectiveness of two recently synthesized inhibitors based on quinoline structures: MPQ (2-methyl-5-(propoxymethyl) quinolin-8-ol) and AAQ ((((2-aminoethyl)amino)methyl)-2-methylquinolin-8-ol) in protecting steel against environmental degradation, particularly in acidic and chloride-rich conditions such as hydrochloric acid. The inhibitors exhibited significant corrosion inhibition efficiencies of 92.37 % for MPQ and 84.13 % for AAQ, as demonstrated through electrochemical analysis. Surface characterization techniques, including SEM-EDX(Scanning Electron Microscopy with Energy Dispersive X-ray analysis), AFM (Atomic Force Microscopy), and contact angle measurements, revealed the formation of a protective barrier film that reduces the corrosion rate. Additionally, theoretical calculations using the Gaussian package provided insights into the adsorption behaviors and protective mechanisms of the inhibitors on mild steel surfaces. The findings contribute to the ongoing search for viable corrosion inhibitors, offering prospects for application in industries and critical infrastructures to enhance corrosion protection and durability.
Anahtar Kelimeler
Adsorption | Corrosion inhibitors | Hydrochloric acid | Mild steel | Quinoline derivatives