Ammonia-responsive thermoplastic starch films incorporated with gallic acid-cobalt metal-organic frameworks (GA/Co-MOF) for real-time tracking of shrimp freshness
 
Yazarlar (5)
Mustafa Tahsin Yılmaz
Faculty Of Engineering, King Abdulaziz University, Türkiye
Mahmud Ekrem Parlak Bursa Teknik Üniversitesi, Türkiye
Zehra İrem Yıldız Bursa Teknik Üniversitesi, Türkiye
Doç. Dr. Oya Irmak CEBECİ Yalova Üniversitesi, Türkiye
Adnan Fatih Dağdelen Bursa Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı International Journal of Biological Macromolecules (Q1)
Dergi ISSN 0141-8130 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili Türkçe Basım Tarihi 01-2026
Cilt / Sayı / Sayfa 338 / 1 / 149551–0 DOI 10.1016/j.ijbiomac.2025.149551
Makale Linki https://www.sciencedirect.com/science/article/pii/S0141813025101086
Özet
Developing ammonia-responsive biopolymer-based smart films with strong mechanical properties and reliable visual freshness indicators is a significant research focus. Integrating cobalt-based metal-organic frameworks (Co-MOF) into a polymer matrix is a contemporary method for manufacturing intelligent packaging materials, primarily due to their rapid responsiveness to ammonia. This study successfully synthesized an ammonia-sensitive Co-MOF by using gallic acid as the ligand (GA/Co-MOF) and integrated them into a thermoplastic starch (TPS) matrix, creating high-performance, multifunctional TPS-based intelligent active composite films (TPS/Co-MOF). FTIR analysis indicates that cobalt exhibits a strong affinity for the carboxy and hydroxy groups of gallic acid, leading to the formation of spherical aggregates, which have diameters of between 600 and 1000 nm, as visualized using SEM. A thorough …
Anahtar Kelimeler
Ammonia sensitive | Material characterization | Metal-organic framework | Smart packaging | Thermoplastic starch