Polyester/clay nanocomposite synthesis via metal-free azide-alkyne click reaction
Yazarlar (4)
Dr. Öğr. Üyesi Reyhan Özdoğan Bursa Teknik Üniversitesi, Türkiye
Özgün Dağlar
İstanbul Teknik Üniversitesi, Türkiye
İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Hakan Durmaz İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Macromolecular Science Part A Pure and Applied Chemistry (Q3) | ||
| Dergi ISSN | 1060-1325 Dergi Bilgileri (2025) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 11-2025 |
| Kabul Tarihi | 23-10-2025 | Yayınlanma Tarihi | 05-11-2025 |
| Cilt / Sayı / Sayfa | 62 / 12 / 1286–1292 | DOI | 10.1080/10601325.2025.2581823 |
| Makale Linki | https://doi.org/10.1080/10601325.2025.2581823 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
Nanoteknoloji
Yüzey Kimyası
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| Özet |
| A polyester/montmorillonite (MMT) nanocomposite is synthesized via metal-free azide-alkyne 1,3-dipolar cycloaddition (metal-free AAC) click reaction. An aliphatic polyester, poly(1,4-butane diol acetylene dicarboxylate), bearing electron-deficient alkyne groups and an azide-functionalized montmorillonite were prepared following literature procedures, then coupled at room temperature for 24 h at varied clay loadings (1, 5, and 10 wt.%) to yield the nanocomposites. Structural, thermal and morphological features of the nanocomposites are evaluated with various characterization techniques. Under nitrogen atmosphere, all nanocomposites showed enhanced thermal stability with one-step degradation, and the char yield increased by ∼30% at the highest clay loading relative to the neat polyester. DSC revealed higher transition temperatures, with melting temperature up by ∼3% and crystallization temperature up … |
| Anahtar Kelimeler |
| Click chemistry | metal-free azide-alkyne 1,3-dipolar cycloaddition | montmorillonite | nanocomposite | polyester |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 1 |
| Google Scholar | 1 |