Thiol-epoxy click chemistry in polymer science
Yazarlar (2)
Dr. Öğr. Üyesi Seda BEKİN AÇAR Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
| Makale Türü | Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri) (SCI, SSCI, AHCI, SCI-Exp dergilerinde yayınlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale) | ||
| Dergi Adı | Journal of Macromolecular Science Part A Pure and Applied Chemistry (Q3) | ||
| Dergi ISSN | 1060-1325 Dergi Bilgileri (2026) | ||
| Dergi Tarandığı Indeksler | |||
| Makale Dili | İngilizce | Basım Tarihi | 01-2026 |
| Kabul Tarihi | 27-11-2025 | Yayınlanma Tarihi | 10-12-2025 |
| Cilt / Sayı / Sayfa | 63 / 2 / 91–100 | DOI | 10.1080/10601325.2025.2598333 |
| Makale Linki | https://doi.org/10.1080/10601325.2025.2598333 | ||
| UAK Araştırma Alanları |
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| Özet |
| Thiol-epoxy click chemistry has emerged as a metal-free, highly efficient approach for polymer science, combining fast kinetics, mild conditions, and broad functional-group tolerance with easy purification. This review summarizes fundamental mechanisms (base-catalyzed anionic, acid-catalyzed Brønsted/Lewis, and proton-transfer--mediated routes), highlighting how catalyst choice controls regioselectivity, cure rate, and side reactions. We investigate the roles of thiol-epoxy chemistry in polymer functionalization (including post-modification of epoxide-bearing backbones), step-growth syntheses ofpoly(β-hydroxy thioether)s via AA/BB and AB strategies, photopatternable networks based on photoinitiation, and hybrid/dual-cure systems coupling thiol-ene with thiol-epoxy to form stress-reduced, high-modulus thermosets. Materials case studies extent miktoarm stars, hydrogels, and nanocomposites reinforced with ... |
| Anahtar Kelimeler |
| Click chemistry | polymer synthesis | polythioethers | thermosets | thiol-epoxy chemistry |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 4 |
| Google Scholar | 5 |