Adsorptive performance of cobalt/manganese oxide modulation via mechanochemical synthesis route on toxic congo red removal

BUĞDAYCI, Mehmet; KANMAZ KELEŞOĞLU, Nergiz Zeynep; BARAN, Pelin; Baslayici, S.

doi:10.1007/s13762-025-06912-5

Adsorptive performance of cobalt/manganese oxide modulation via mechanochemical synthesis route on toxic congo red removal

Yazarlar (4)

Doç. Dr. Mehmet BUĞDAYCI Yalova Üniversitesi, Türkiye

Arş. Gör. Dr. Nergiz Zeynep KANMAZ KELEŞOĞLU Yalova Üniversitesi, Türkiye

Prof. Dr. Pelin BARAN Yalova Üniversitesi, Türkiye

S. Baslayici
İstanbul Medipol Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	International Journal of Environmental Science and Technology (Q3)
Dergi ISSN	1735-1472 Dergi Bilgileri (2025)
Makale Dili	İngilizce	Basım Tarihi	11-2025
Cilt / Sayı / Sayfa	23 / 1 / –	DOI	10.1007/s13762-025-06912-5
UAK Araştırma Alanları

Özet

In this study, cobalt oxide (Co3O4) and manganese oxide (MnO) were employed for synthesizing hybrid oxides CoMnOx using a ball-milling technique and evaluated for congo red (CR) removal. The prepared adsorbent samples were characterized by using XRD, SEM–EDX, BET/N2, FT-IR, and XPS to determine their structural, morphological, and chemical properties. Adsorption studies were carried out to optimize the parameters of adsorbent dosage, time, pH, temperature and different water matrices. The obtained results demonstrated that CoMnOx2 exhibited the highest adsorption capacity of 218.54 mg g⁻¹ following the Langmuir model. Kinetic studies revealed that adsorption reached equilibrium at 300 min and was supported by the Elovich model, meaning that chemical interactions were dominant. Adsorption process was exothermic and spontaneous at low temperatures. Despite the presence of anions and cations in the water medium, it showed effective removal. CoMnOx2 maintained stable performance for five cycles and also performed well in removing different pollutants.

Anahtar Kelimeler

Adsorption | Ball-milling | Cobalt oxide | Congo red | Manganese oxide

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	2
Scopus	3

Adsorptive performance of cobalt/manganese oxide modulation via mechanochemical synthesis route on toxic congo red removal

Dergi Adı	International Journal of Environmental Science and Technology
Kısa Adı	INT J ENVIRON SCI TE
Yayıncı	SPRINGER
Açık Erişim	Hayır
ISSN	1735-1472
E-ISSN	1735-2630
Wos Quartile	Q3
Scopus Quartile	Q1
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	ENVIRONMENTAL SCIENCES
Scopus Kategoriler	AGRICULTURAL AND BIOLOGICAL SCIENCES (MISCELLANEOUS) \| ENVIRONMENTAL CHEMISTRY \| ENVIRONMENTAL ENGINEERING