Click Chemistry in Macromolecular Design: Complex Architectures from Functional Polymers
Yazarlar (2)
Doç. Dr. Mehmet ARSLAN Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Atilla TAŞDELEN Yalova Üniversitesi, Türkiye
Makale Türü Diğer (Teknik, not, yorum, vaka takdimi, editöre mektup, özet, kitap krıtiği, araştırma notu, bilirkişi raporu ve benzeri) (SCOPUS dergilerinde yayınlanan teknik not, editöre mektup, tartışma, vaka takdimi ve özet türünden makale)
Dergi Adı Chemistry Africa
Dergi ISSN 2522-5758 Dergi Bilgileri (2019)
Makale Dili İngilizce Basım Tarihi 06-2019
Cilt / Sayı / Sayfa 2 / 2 / 195–214 DOI 10.1007/s42250-018-0030-8
UAK Araştırma Alanları
Özet
This contribution reviews the applications of click chemistry reactions in design and synthesis of various macromolecular architectures that hold key aspects in polymer science. By considering the emerging concepts that shape how synthetic polymer chemistry and macromolecular engineering utilize ‘reactions’ in ‘fabrication’, in the last decade, the click chemistry methodologies have been pioneered the chemical approaches that allow to access diverse complex macromolecules. The common and leading features of click chemistry reactions rely on efficient, fast, selective and easy to implement chemical transformations giving very high to quantitative coupling efficiencies. These are essential virtues that provide triumphing in macromolecular engineering, since the building blocks are usually large polymer chains. For the efficient building of complex macromolecules via click reactions, properly functionalized polymers are key components in which special design is required to successful installation of ‘clickable’ reactive groups on polymer end groups or side chains. In this report, the synthetic methods encompassing various click chemistry reactions in fabrication and applications of a range of complex macromolecular architectures have been reviewed.
Anahtar Kelimeler
Click chemistry | Complex macromolecular architectures | Functional polymers | Polymer modification