| Makale Türü | Özgün Makale (Uluslararası alan indekslerindeki dergilerde yayınlanan tam makale) | ||
| Dergi Adı | |||
| Makale Dili | – | Basım Tarihi | 04-2013 |
| Makale Linki | https://books.rsc.org/books/edited-volume/1928/chapter/2550550 | ||
| UAK Araştırma Alanları |
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| Özet |
| In an attempt to combine the advantages of living polymerization with the flexibility of free radical polymerization, there has been a significant amount of research into the possibility of controlled/living radical polymerization (C/LRP). These polymerization methods1–4 allow nearly unlimited control of the polymer’s composition, architecture and functionality. 5 It seems possible nowadays to prepare various novel architectures from virtually all kinds of vinyl monomers by C/LRP methods in common mass, suspension or even emulsion processes. Control over radical polymerization of vinyl monomers was firstly attempted in 1955 by Ferington and Tobolsky. 6 These authors observed that dithiuram disulfides in radical polymerizations lead to higher transfer constants, which resulted in retardation of the polymerization. Borsig et al. 7 reported more evidence of C/LRP; the use of diaryl and triaryl protected groups in the … |
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