Orthogonal Synthesis of Block Copolymer via Photoinduced CuAAC and Ketene Chemistries
Yazarlar (3)
Prof. Dr. Mehmet Atilla TAŞDELEN
Yalova Üniversitesi, Türkiye
Kırklareli Üniversitesi, Türkiye
Doç. Dr. Cumali ÇELİK
Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Macromolecular Rapid Communications |
| Dergi ISSN | 1022-1336 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 03-2016 |
| Cilt No | 37 |
| Sayı | 6 |
| Sayfalar | 521 / 526 |
| DOI Numarası | 10.1002/marc.201500563 |
| Makale Linki | http://dx.doi.org/10.1002/marc.201500563 |
| Özet |
| A novel route for the synthesis of poly(ethylene glycol)-b-polystyrene copolymer, starting from commercially available poly(ethylene glycol) methyl ether and azido terminated polystyrene prepared by atom transfer radical polymerization and subsequent nucleophilic substitution, is applied with simplicity and high efficiency. The combination of photoinduced copper (I)-catalyzed alkyne-azide cycloaddition (CuAAC) and ketene chemistry reactions proceeds either simultaneously or sequentially in a one-pot procedure under near-visible light irradiation. In both cases, excellent block copolymer formations are achieved, with an average molecular weight of around 7000 g mo1(-1) and a polydispersity index of 1.20. |
| Anahtar Kelimeler |
| block copolymers | click chemistry | copper-catalyzed azide-alkyne cycloaddition | ketene chemistry | photochemical reactions |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 13 |