Poly(p-aminobenzyl alcohol) Films with and without Organic Compound on AISI 316 Surface; Synthesis and the Corrosion Performances    
Yazarlar (3)
Ali Tuncay Özyılmaz
Türkiye
Begüm Özgen
Doç. Dr. Cumali ÇELİK Yalova Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale
Makale Alt Türü Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayınlanan tam makale
Dergi Adı Journal of the Turkish Chemical Society, Section A: Chemistry
Dergi ISSN 2149-0120 Scopus Dergi
Dergi Tarandığı Indeksler TR DİZİN
Makale Dili İngilizce
Basım Tarihi 03-2020
Cilt No 7
Sayı 2
Sayfalar 375 / 382
DOI Numarası 10.18596/jotcsa.641851
Makale Linki http://dx.doi.org/10.18596/jotcsa.641851
Özet
In this work, we obtained the anticorrosive properties of polymer films (SS/PABA and SS/PABAORG) synthesized on stainless steel surface by adding an organic substance to aniline derived oaminobenzyl alcohol monomer synthesis medium. Firstly, we prepared the polymer coating bath bydissolving 0.15 M o -aminobenzyl alcohol monomer in the electrolyte solvent containing acetonitrile and0.15 M LiClO4. From this bath, poly (o-aminobenzyl alcohol) (PABA) film was synthesized in 30 segments bycyclic voltammetry (CV) technique at a scanning rate of 50 mV/s at a potential range of -0.20/1.80 V on theAISI 316 (SS) working electrode in contrast to the platinum electrode. For the synthesis of organic structuredoped polymer film (PABA-ORG), we repeated the same synthesis process by dissolving C21H27NO2(k) (ORG)at low concentration in the same bath. We investigated the corrosion performances of bare SS, SS/PABA,and SS/PABA-ORG substrates, using open circuit potential – time, anodic polarization, and AC impedancetechniques in the solution of corrosion study. As a result, we observed that the organic additive added tothe synthesis medium caused changes in the synthesis behavior of PABA. Corrosion performance testsshowed that PABA and PABA-ORG films increased the corrosion protection performance of the SS electrode,and we observed a reduction of the corrosion rate of the SS electrode.
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