Synthesis of PolyHIPEs from Photocurable Water-in-Oil High Internal Phase Emulsions by Using a Sustainable Monomer: β-Myrcene
Yazarlar (3)
Meltem Sözbir Yalova Üniversitesi, Türkiye
Burcu Kekevi Yalova Üniversitesi, Türkiye
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Polymers and the Environment (Q1)
Dergi ISSN 1566-2543 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 04-2023
Kabul Tarihi 25-03-2023 Yayınlanma Tarihi 07-04-2023
Cilt / Sayı / Sayfa 31 / 8 / 3677–3687 DOI 10.1007/s10924-023-02855-5
Makale Linki http://dx.doi.org/10.1007/s10924-023-02855-5
UAK Araştırma Alanları
Polimer Bilimi
Özet
Recently, there has been an increasing interest in the synthesis of bio-derived and sustainable polymers due to limited petroleum resources and the dependence of polymer chemistry on fossil fuels. Terpenes which are found in nature in wide variety of structures, are a large family derived from plants. Isoprene like structure of terpenes make these natural compounds susceptible to polymerization. In this work, β-myrcene, which is an acyclic monoterpene was used in the synthesis of photocurable porous polymer monoliths via high internal phase emulsion (HIPE) templating. Photocuring of β-myrcene in HIPE templates has been achieved by the free radical copolymerization crosslinking reaction with 1,4-butanediol dimethacrylate (1,4-BDDMA). To determine the effect of monomer ratio on the crosslink density and pore morphology of the resulting polyHIPEs, the volume ratio of β-myrcene in the external phase has …
Anahtar Kelimeler
Crosslink density | Emulsion templating | Photopolymerization | PolyHIPE | β-myrcene