Synthesis of PolyHIPEs from Photocurable Water-in-Oil High Internal Phase Emulsions by Using a Sustainable Monomer: β-Myrcene
Yazarlar (3)
Meltem Sözbir
Yalova Üniversitesi, Türkiye
Doç. Dr. Burcu KEKEVİ
Yalova Üniversitesi, Türkiye
Prof. Dr. Emine Hilal MERT
Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Polymers and the Environment (Q1) | ||
| Dergi ISSN | 1566-2543 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2023 |
| Cilt / Sayı / Sayfa | 31 / 8 / 3677–3687 | DOI | 10.1007/s10924-023-02855-5 |
| Makale Linki | http://dx.doi.org/10.1007/s10924-023-02855-5 | ||
| Özet |
| Recently, there has been an increasing interest in the synthesis of bio-derived and sustainable polymers due to limited petroleum resources and the dependence of polymer chemistry on fossil fuels. Terpenes which are found in nature in wide variety of structures, are a large family derived from plants. Isoprene like structure of terpenes make these natural compounds susceptible to polymerization. In this work, β-myrcene, which is an acyclic monoterpene was used in the synthesis of photocurable porous polymer monoliths via high internal phase emulsion (HIPE) templating. Photocuring of β-myrcene in HIPE templates has been achieved by the free radical copolymerization crosslinking reaction with 1,4-butanediol dimethacrylate (1,4-BDDMA). To determine the effect of monomer ratio on the crosslink density and pore morphology of the resulting polyHIPEs, the volume ratio of β-myrcene in the external phase has been varied from 10 to 90. Crosslink density of the polyHIPEs has been calculated by swelling experiments using Flory-Rehner Theory. In the end, polyHIPEs exhibiting pore morphology constituted of cavities and interconnected pores has been obtained in all cases. However, it has been determined that 60% is the optimum β-myrcene ratio to obtain a highly crosslinked polyHIPE accompanied with an open-cellular pore morphology. |
| Anahtar Kelimeler |
| Crosslink density | Emulsion templating | Photopolymerization | PolyHIPE | β-myrcene |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 5 |
| Google Scholar | 6 |