Preparation of functional unsaturated polyester co glycidyl methacrylate co divinylbenzene polyHIPE beads through w o w multiple emulsions preparation characterization and application
Yazarlar (2)
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
Hüseyin Yıldırım Yalova Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı E Polymers (Q2)
Dergi ISSN 1618-7229 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2014
Kabul Tarihi Yayınlanma Tarihi 01-01-2014
Cilt / Sayı / Sayfa 14 / 1 / 65–73 DOI 10.1515/epoly-2013-0071
Makale Linki https://www.degruyter.com/document/doi/10.1515/epoly-2013-0071/pdf
Özet
Poly(unsaturated polyester-co-glycidyl methacrylate-co-divinylbenzene) poly high internal phase emulsion (HIPE) beads were synthesized via water-in-oil-in-water (w/o/w) multiple emulsions. HIPEs were prepared by using a commercial unsaturated polyester resin (UPR) and a mixture of glycidyl methacrylate (GMA) and divinylbenzene (DVB) as the cross-linker. The external surfactant was found to be a strong influence on the morphology of the beads. The porosity and the pore morphology of the resulting polyHIPE beads were investigated by scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) molecular adsorption method, respectively. Post-functionalization of the beads was carried out with multifunctional amines such as 1,4-ethylenediamine (EDA), 1,6-hexamethylenediamine (HMDA) and 4-aminosalicylic acid (ASA). Elemental analysis was used to confirm the functionalization. Resulting …
Anahtar Kelimeler
Metal adsorption | Multifunctional amine | PolyHIPE bead | Unsaturated polyester resin | W/o/w emulsion