Preparation of functional unsaturated polyester co glycidyl methacrylate co divinylbenzene polyHIPE beads through w o w multiple emulsions preparation characterization and application
Yazarlar (2)
Prof. Dr. Emine Hilal MERT
Yalova Üniversitesi, Türkiye
Hüseyin Yıldırım
Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | E Polymers (Q2) | ||
| Dergi ISSN | 1618-7229 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2014 |
| Cilt / Sayı / Sayfa | 14 / 1 / 65–73 | DOI | 10.1515/epoly-2013-0071 |
| Özet |
| Poly(unsaturated polyester-co-glycidyl meth-acrylate-co-divinylbenzene) poly high internal phase emulsion (HIPE) beads were synthesized via water-in-oil-in-water (w/o/w) multiple emulsions. HIPEs were prepared by using a commercial unsaturated polyester resin (UPR) and a mixture of glycidyl methacrylate (GMA) and divinylbenzene (DVB) as the cross-linker. The external surfactant was found to be a strong influence on the morphology of the beads. The porosity and the pore morphology of the resulting polyHIPE beads were investigated by scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) molecular adsorption method, respectively. Post-functionalization of the beads was carried out with multifunctional amines such as 1,4-ethylenediamine (EDA), 1,6-hexamethylenediamine (HMDA) and 4-aminosalicylic acid (ASA). Elemental analysis was used to confirm the functionalization. Resulting functional beads were tested on the adsorption of Ag(I), Cu(II), and Cr(III) under non-competitive conditions and atomic absorption spectroscopy (AAS) was used to calculate the adsorption capacities. The maximum adsorption capacities of the functional beads were found to be decreasing in the order of Ag(I)>Cu(II)>Cr(III). |
| Anahtar Kelimeler |
| Metal adsorption | Multifunctional amine | PolyHIPE bead | Unsaturated polyester resin | W/o/w emulsion |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| SCOPUS | 18 |
| Google Scholar | 24 |