Influence of titania on the morphological and mechanical properties of 1,3-butanediol dimethacrylate based polyHIPE composites
Yazarlar (5)
Elif Yüce
Yalova Üniversitesi, Türkiye
Fatma Nur Parın Bursa Teknik Üniversitesi, Türkiye
Peter Krajnc
Univerza V Mariboru, Slovenya
H. Hande Mert
Yalova Üniversitesi, Türkiye
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Reactive and Functional Polymers (Q1)
Dergi ISSN 1381-5148 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 05-2018
Kabul Tarihi Yayınlanma Tarihi 01-09-2018
Cilt / Sayı / Sayfa 130 / 1 / 8–15 DOI 10.1016/j.reactfunctpolym.2018.05.009
Makale Linki https://www.sciencedirect.com/science/article/pii/S1381514818301305
Özet
Macroporous polymer/TiO2 composites were synthesized by the polymerisation of 1,3-butanediol dimethacrylate (1,3-BDDMA) based water-in-oil high internal phase emulsions. High internal phase emulsions (HIPEs) having 80 vol% of internal phase were used as templates for inducing porosity in the resulting polymer composites. Apart from the monomer, either methyl methacrylate (MMA) or 2-ethylhexyl acrylate (EHA) was used as a co-monomer. In order to investigate the influence of nanoparticle loading on the morphological and mechanical properties of highly porous polymers, 1 to 10 wt% of colloidal TiO2 nanoparticles were introduced into emulsion templates. It was found that increasing the amount of nanoparticle loading from 1 wt% to 10 wt%, average cavity sizes decreased from 14.1 μm to 5.9 μm in the case of MMA co-monomer, and from 18.6 μm to 5.1 μm in the case of EHA co-monomer …
Anahtar Kelimeler
Nanocomposites | polyHIPE | Porous polymers | Regression analysis | Titania