Influence of titania on the morphological and mechanical properties of 1,3-butanediol dimethacrylate based polyHIPE composites

Yüce, Elif; Parın, Fatma Nur; Krajnc, Peter; Mert, H. Hande; MERT, Emine Hilal

doi:10.1016/j.reactfunctpolym.2018.05.009

Influence of titania on the morphological and mechanical properties of 1,3-butanediol dimethacrylate based polyHIPE composites

Yazarlar (5)

Elif Yüce Yalova Üniversitesi, Türkiye

Fatma Nur Parın Bursa Teknik Üniversitesi, Türkiye

Peter Krajnc Univerza V Mariboru, Slovenya

H. Hande Mert Yalova Üniversitesi, Türkiye

Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Reactive and Functional Polymers (Q1)
Dergi ISSN	1381-5148 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI
Makale Dili	İngilizce	Basım Tarihi	05-2018
Cilt / Sayı / Sayfa	130 / 1 / 8–15	DOI	10.1016/j.reactfunctpolym.2018.05.009
Makale Linki	https://www.sciencedirect.com/science/article/pii/S1381514818301305

Özet

Macroporous polymer/TiO2 composites were synthesized by the polymerisation of 1,3-butanediol dimethacrylate (1,3-BDDMA) based water-in-oil high internal phase emulsions. High internal phase emulsions (HIPEs) having 80 vol% of internal phase were used as templates for inducing porosity in the resulting polymer composites. Apart from the monomer, either methyl methacrylate (MMA) or 2-ethylhexyl acrylate (EHA) was used as a co-monomer. In order to investigate the influence of nanoparticle loading on the morphological and mechanical properties of highly porous polymers, 1 to 10 wt% of colloidal TiO2 nanoparticles were introduced into emulsion templates. It was found that increasing the amount of nanoparticle loading from 1 wt% to 10 wt%, average cavity sizes decreased from 14.1 μm to 5.9 μm in the case of MMA co-monomer, and from 18.6 μm to 5.1 μm in the case of EHA co-monomer. Moreover, it was found that introducing 1 wt% of nanoparticle significantly improved the mechanical properties of both MMA and EHA copolymerized polyHIPEs. In order to explain the influence of nanoparticle loading and comonomer type on the physical properties appropriate regression analyses were conducted.

Anahtar Kelimeler

Nanocomposites | polyHIPE | Porous polymers | Regression analysis | Titania

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
SCOPUS	24
Google Scholar	29

Influence of titania on the morphological and mechanical properties of 1,3-butanediol dimethacrylate based polyHIPE composites

Dergi Adı	REACTIVE & FUNCTIONAL POLYMERS
Yayıncı	Elsevier B.V.
Açık Erişim	Hayır
ISSN	1381-5148
E-ISSN	1873-166X
CiteScore	8,6
SJR	0,876
SNIP	0,942

Influence of titania on the morphological and mechanical properties of 1,3-butanediol dimethacrylate based polyHIPE composites

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