Tailoring the mechanical and thermal properties of dicyclopentadiene polyHIPEs with the use of a comonomer
    
Yazarlar (3)
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
C. Slugovc Institut Für Chemische Technologie Von Materialien, Avusturya
P. Krajnc Univerza V Mariboru, Slovenya
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Express Polymer Letters (Q1)
Dergi ISSN 1788-618X Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2015
Cilt / Sayı / Sayfa 9 / 4 / 344–353 DOI 10.3144/expresspolymlett.2015.32
Makale Linki http://www.expresspolymlett.com/letolt.php?file=EPL-0005580&mi=c
Özet
The effect of adding a comonomer to dicyclopentadiene in high internal phase emulsions (HIPEs) on the properties of ring-opening metathesis polymerisation (ROMP) derived polyHIPEs has been investigated. With this aim, dicylopentadiene was copolymerised with norbornene in surfactant stabilized high internal phase emulsions. Morphological, mechanical and thermal properties of the resulting materials were investigated with regard to the monomer ratio. The interconnected pore structure was observed for the resulting poly(dicylopentadiene-co-norbornene) polyHIPEs. Furthermore, the new polyHIPE copolymers were found to have an improved thermal stability compared to the poly(dicylopentadiene) homopolymer.
Anahtar Kelimeler
Dicyclopentadiene | Emulsion templating | Mechanical properties | Norbornene | polyHIPE