Utilization of copper-coordinated metal-organic framework materials for crystal violet removal: Modeling using box-behnken experimental design

Şimşiroğlu, Şebnem; Aslan, Taner; Yalçın, Berrin Saygı; Erçağ, Erol; HIZAL YÜCESOY, Fehime Jülide

doi:10.1016/j.flatc.2025.100950

Utilization of copper-coordinated metal-organic framework materials for crystal violet removal: Modeling using box-behnken experimental design

Yazarlar (5)

Şebnem Şimşiroğlu
Yalova Üniversitesi, Türkiye

Prof. Dr. Taner Aslan Ignis Nano Yazılım Teknoloji A.Ş., Türkiye

Berrin Saygı Yalçın Yalova Üniversitesi, Türkiye

Prof. Dr. Erol Erçağ Istanbul University-Cerrahpasa, Türkiye

Prof. Dr. Fehime Jülide HIZAL YÜCESOY Yalova Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Flatchem (Q2)
Dergi ISSN	2452-2627 Dergi Bilgileri (2025)
Dergi Tarandığı Indeksler	SCI-Expanded
Makale Dili	İngilizce	Basım Tarihi	10-2025
Kabul Tarihi	–	Yayınlanma Tarihi	01-11-2025
Cilt / Sayı / Sayfa	54 / 1 / –	DOI	10.1016/j.flatc.2025.100950
Makale Linki	https://doi.org/10.1016/j.flatc.2025.100950
UAK Araştırma Alanları	Analitik Kimya

Özet

This study aims to evaluate the effectiveness of pyromellitic diimide carboxylic acid-derived with high retention capacity MOFs as adsorbents for contaminant removal, employing CV as a model pollutant. The adsorbents were synthesized by individually treating the organic linkers with Cu(II) solution at 100–110 °C for 12 h. The characterization of the adsorbents was conducted using FTIR, SEM, PXRD, TGA, BET/N2 surface area analysis, zeta potential measurement, and potentiometric titration. The specific surface areas were determined to be 780.64 m²/g for PDBA-Cu and 445.69 m²/g for PDPA-Cu. The sorption properties of the produced adsorbents were analyzed, considering contact time, initial concentration, pH, and temperature. The adsorptions fitted to the PSOM, exhibiting k values of 0.001 and 0.002 for PDBA-Cu and PDPA-Cu, respectively, in conjunction with the presence of pore diffusion. The CV adsorption on PDPA-Cu conformed to the Freundlich isotherm and had Langmuir characteristics for PDBA-Cu. The Qmax values were yielded as 322.58 mg/g for PDBA-Cu and 400.00 mg/g for PDPA-Cu at 313 K. The maximum adsorptions were achieved at pH levels between 2 and 7 for PDBA-Cu and between 2 and 9 for PDPA-Cu. Electrostatic and π-π interactions have played a role in the CV adsorption on fabricated MOFs. The adsorptions were optimized via modeling with Response Surface Methodology and Box-Behnken Design, based on the critical process variables of contact time, temperature, and initial dye concentration. The findings of this study validated the superior efficacy of the synthesized MOFs in eliminating cationic organic dyes and their applicability in treatment methods.

Anahtar Kelimeler

adsorption | CV | Elovich | interaction | MOF

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	3
Scopus	3

Utilization of copper-coordinated metal-organic framework materials for crystal violet removal: Modeling using box-behnken experimental design

Dergi Adı	FlatChem
Kısa Adı	FLATCHEM
Yayıncı	ELSEVIER
Açık Erişim	Hayır
ISSN	2452-2627
E-ISSN	2452-2627
Wos Quartile	Q2
Scopus Quartile	Q1
Tarandığı Indeksler	SCIE , Scopus
WoS Kategoriler	CHEMISTRY, PHYSICAL \| MATERIALS SCIENCE, MULTIDISCIPLINARY
Scopus Kategoriler	CERAMICS AND COMPOSITES \| ELECTRONIC, OPTICAL AND MAGNETIC MATERIALS \| MATERIALS CHEMISTRY \| SURFACES, COATINGS AND FILMS