Recovery of copper II and chromium III VI from electroplating industry wastewater by ion exchange
Yazarlar (4)
Doç. Dr. Sibel Yalçin Istanbul Üniversitesi, Türkiye
Reşat Apak Istanbul Üniversitesi, Türkiye
Prof. Dr. Fehime Jülide HIZAL YÜCESOY Istanbul Üniversitesi, Türkiye
Hüseyin Afşar
Yıldız Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Separation Science and Technology (Q2)
Dergi ISSN 0149-6395 Dergi Bilgileri (2001)
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 01-2001
Kabul Tarihi – Yayınlanma Tarihi 31-08-2001
Cilt / Sayı / Sayfa 36 / 10 / 2181–2196 DOI 10.1081/SS-100105912
Makale Linki http://www.tandfonline.com/doi/abs/10.1081/SS-100105912
UAK Araştırma Alanları
Analitik Kimya
Özet
Two laboratory-scale separation processes have been developed for the recovery of copper (II) from acidic and cyanide-containing alkaline wastewater of electroplating industries. Acidic bath wastes were treated with Dowex 50X8, a strongly acidic cation-exchange resin, and the retained copper was eluted with H2SO4. The cyanide-containing alkaline bath waste was first oxidized with excessive hypochlorite, then neutralized, and recovered by the use of Amberlite IRC-718 chelating resin. Copper was eluted with H2SO4. The two different valencies of chromium have been recovered from electroplating-industry wastewater by different separation processes: The predominant valency, Cr(VI), was retained on a strongly basic Dowex 1X8 resin and eluted with a NaCl and NaOH solution. Alternatively, Cr(III), either existing originally in electroplating-industry waste-rinse mixtures or converted from Cr(VI) by reduction with Na2SO3, could be recovered by a weakly acidic Amberlite IRC-50 resin and eluted with a solution containing H2O2and NaOH. Where plating industry wastes contain high levels of organic contamination, Cr(VI) would be naturally reduced to Cr(III) upon acidification, and it may be more economical to recover all chromium as Cr(III).
Anahtar Kelimeler
Chromium (III) | Chromium (VI) | Copper (II) | Electroplating-industry wastewater | Ion exchange | Recovery | Removal | Wastewater treatment
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 56
Scopus 66
Recovery of copper II and chromium III VI from electroplating industry wastewater by ion exchange