Fluorescent Polymeric Sensor for Selective and Sensitive Detection of Cu(II) ions in Aqueous Medium
Yazarlar (5)
Prof. Dr. Soner Çubuk Marmara Üniversitesi, Türkiye
Nur Koçoğlu
Marmara Üniversitesi, Türkiye
Doç. Dr. Gülay BAYRAMOĞLU Yalova Üniversitesi, Türkiye
Doç. Dr. Hatice Birtane Marmara Üniversitesi, Türkiye
M. Vezir Kahraman
Marmara Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SCOPUS dergilerinde yayınlanan tam makale)
Dergi Adı Journal of the Turkish Chemical Society Section A Chemistry
Dergi ISSN 2149-0120 Dergi Bilgileri (2024)
Dergi Tarandığı Indeksler TR DİZİN
Makale Dili İngilizce Basım Tarihi 01-2024
Kabul Tarihi 05-12-2023 Yayınlanma Tarihi 04-02-2024
Cilt / Sayı / Sayfa 11 / 1 / 377–390 DOI 10.18596/jotcsa.1324839
Makale Linki https://dergipark.org.tr/en/pub/jotcsa/issue/80874/1324839
UAK Araştırma Alanları
Polimer Bilimi
Özet
In our study, a selective and sensitive determination method was developed for Cu(II) ions by spectrofluorimetry. For this purpose, a polymeric membrane was prepared to determine Cu(II) ions by curing crosslinkers, functional monomers, and photoinitiators under UV light. The membrane was characterized, and the optimum conditions for determining Cu(II) ions were systematically investigated. The detection was performed at pH 5.0 in as little as 20 seconds at excitation and emission wavelengths of 376 nm and 455 nm, respectively. The linear range was 7.86.10-9-1.57.10-7 mol/L, and the method's detection limit was 2.24.10-9 mol/L. In addition, the sensor's repeatability, stability, and life were examined, and recovery studies were conducted. As a result, the developed method has been successfully applied to wastewater samples as a real sample. In addition, determining Cu(II) ions at low concentrations can be done quickly, reliably, and with high selectivity and sensitivity.
Anahtar Kelimeler
Cu(II) determination | fluorimetric sensor | photocuring | polymeric membrane