PAMPSA IM based proton conducting polymer electrolytes
Yazarlar (3)
Prof. Dr. Hamit ERDEMİ Fatih Üniversitesi, Türkiye
A. Bozkurt
Fatih Üniversitesi, Türkiye
W. H. Meyer
Max Planck Institute For Polymer Research, Almanya
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Synthetic Metals (Q2)
Dergi ISSN 0379-6779 Dergi Bilgileri (2004)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2004
Kabul Tarihi – Yayınlanma Tarihi 01-05-2004
Cilt / Sayı / Sayfa 143 / 1 / 133–138 DOI 10.1016/j.synthmet.2003.10.022
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0379677903005083
UAK Araştırma Alanları
Polimer Bilimi
Özet
The synthesis, thermal and conduction properties of blends of poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPSA) with imidazol (Im) are reported. PAMPSA-xIm blends were prepared for 0.5≤x≤2, where x was the number of moles of imidazol per polymer repeat unit. These blends can be cast into homogeneous films. The protonation of imidazol was demonstrated by FT-IR studies. Thermogravimetric analysis (TG) illustrated that these blends are chemically stable up to about 180°C. Differential scanning calorimetry (DSC) shows that the softening temperature of the blends decreases from 87°C for x=0.5 to -25°C for x=2. The alternating current (ac) conductivities of the samples were measured via impedance spectroscopy. The direct current (dc) conductivity increases with x and temperature reaching 1.45×10 -3S/cm for x=2 at 100°C. © 2003 Elsevier B.V. All rights reserved.
Anahtar Kelimeler
Imidazole | Poly(2-acrylamido-2-methyl-1-propanesulfonic acid) | Proton conductor
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Scopus 51
PAMPSA IM based proton conducting polymer electrolytes