New type of anhydrous organic electrolyte based on carboxylic acid functional triazole as model system
Yazarlar (6)
Melike Türk
Fatih Üniversitesi, Türkiye
Fatih Üniversitesi, Türkiye
Sedat Coşgun
Fatih Üniversitesi, Türkiye
Fatih Üniversitesi, Türkiye
Sevim Ünügür Çelik Fatih Üniversitesi, Türkiye
Prof. Dr. Hamit ERDEMİ Yalova Üniversitesi, Türkiye
Christine Gerardin Charbonnier Université De Lorraine, Fransa
Ayhan Bozkurt Fatih Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Synthetic Metals (Q2) | ||
| Dergi ISSN | 0379-6779 Dergi Bilgileri (2011) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 05-2011 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-05-2011 |
| Cilt / Sayı / Sayfa | 161 / 9 / 665–669 | DOI | 10.1016/j.synthmet.2011.01.010 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0379677911000245 | ||
| UAK Araştırma Alanları |
Polimer Bilimi
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| Özet |
| The model system of dicarboxylic acid functionalized 1H-1,2,3-triazole- terminated alkyl oligomers is presented as a new approach for obtaining high proton conductivity in proton solvating heterocycles covalently bound via spacers. The model materials have been characterized by FT-IR and NMR spectroscopy. Thermal stabilities were examined with thermogravimetric analysis (TGA). Differential scanning calorimetry (DSC) was used to measure melting and crystallization temperatures. The influence of spacer length on proton conductivity was investigated by AC impedance spectroscopy. Analysis of conductivity and permittivity measurements revealed the contribution of local dynamics and proton mobility on conduction mechanism which gives rise to proton conductivities of up to 10-5 S/cm at 120 °C in completely water-free pristine materials. © 2011 Elsevier B.V. |
| Anahtar Kelimeler |
| Organic electrolyte | Permittivity | Proton conductivity | Proton solvent | Triazole |
Science Direct
New type of anhydrous organic electrolyte based on carboxylic acid functional triazole as model system
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 10 |