Synthesis and conductivity studies of piperidine 4 carboxylic acid functionalized Fe3O4 nanoparticles
Yazarlar (4)
Prof. Dr. Hamit ERDEMİ Yalova Üniversitesi, Türkiye
A. Baykal
Fatih Üniversitesi, Türkiye
E. Karaoglu
Fatih Üniversitesi, Türkiye
M. S. Toprak
The Royal Institute of Technology (Kth), İsveç
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Materials Research Bulletin (Q2)
Dergi ISSN 0025-5408 Dergi Bilgileri (2012)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 09-2012
Kabul Tarihi – Yayınlanma Tarihi 01-09-2012
Cilt / Sayı / Sayfa 47 / 9 / 2193–2199 DOI 10.1016/j.materresbull.2012.06.006
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0025540812004448
UAK Araştırma Alanları
Polimer Bilimi
Özet
Piperidine-4-carboxylic acid (PPCA) functionalized Fe 3O 4 nanoparticles as a novel organic-inorganic hybrid was fabricated and characterized by XRD, FT-IR, VSM, and TEM techniques. Its detailed electrical properties are also presented. Composition was determined as Fe 3O 4, while particles were observed to have spherical morphology. VSM measurement proved the super-paramagnetic property of the as synthesized nanocomposite. ac and dc conductivity measurements indicated semiconductor characteristics and changing trends with temperature because of reorganization of the nanocomposite. dc conductivity is strongly temperature dependent and is classified into three regions. Analysis of the real and imaginary parts of the permittivity of nanocomposite showed the ionic polarization mechanism consisting of ionic conductivity and interfacial polarization. © 2012 Elsevier Ltd.
Anahtar Kelimeler
A. Magnetic materials | B. Chemical synthesis | C. Impedance spectroscopy | D. Electrical properties