Tetradecanoic acid‐based polydicyclopentadiene foam supported composite phase change materials: preparation and characterization
Yazarlar (4)
Öğr. Gör. Meltem SÖZBİR Yalova Üniversitesi, Türkiye
Prof. Dr. Hatice Hande MERT Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Selçuk MERT Yalova Üniversitesi, Türkiye
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polymer International (Q2)
Dergi ISSN 0959-8103 Dergi Bilgileri (2025)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2025
Cilt / Sayı / Sayfa 74 / 9 / 839–847 DOI 10.1002/pi.6784
Makale Linki https://doi.org/10.1002/pi.6784
UAK Araştırma Alanları
Malzeme Bilimi ve Teknolojileri
Özet
Water‐in‐oil Pickering high internal phase emulsion (Pickering‐HIPE) of dicylopentadiene (DCPD) was prepared by using block copolymer surface‐modified calcite (mCalcite) particles. To evaluate the contribution of mCalcite particles comparatively, a neat polyHIPE was first synthesized from a conventional DCPD‐based water‐in‐oil HIPE. SEM analysis demonstrated that polymerization of DCPD‐based HIPE and Pickering‐HIPE yielded open‐porous supporting materials. Mechanical tests showed that mCalcite incorporation significantly improved the compressive modulus of the obtained material compared to the neat support. Tetradecanoic acid (TDA) was used as phase change material (PCM) and was successfully incorporated into the synthesized supporting foams via a solvent‐assisted vacuum process. TDA presence in the composite PCM foams, named polyDCPD/TDA and polyDCPD/mCalcite/TDA, was ...
Anahtar Kelimeler
calcite | dicyclopentadiene | emulsion templating | phase change material | tetradecanoic acid