Renewable terpene-based highly porous polymer monoliths for the effective removal of persistent pharmaceuticals of tetracycline and ibuprofen
Yazarlar (6)
Öğr. Gör. Meltem SÖZBİR Yalova Üniversitesi, Türkiye
Esra Bilgin Şimşek Yalova Üniversitesi, Türkiye
Prof. Dr. Hatice Hande MERT Yalova Üniversitesi, Türkiye
Doç. Dr. Burcu KEKEVİ Yalova Üniversitesi, Türkiye
Prof. Dr. Mehmet Selçuk MERT Yalova Üniversitesi, Türkiye
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Microporous and Mesoporous Materials (Q1)
Dergi ISSN 1387-1811 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 04-2023
Kabul Tarihi Yayınlanma Tarihi 01-04-2023
Cilt / Sayı / Sayfa 354 / 1 / 112509–0 DOI 10.1016/j.micromeso.2023.112509
Makale Linki http://dx.doi.org/10.1016/j.micromeso.2023.112509
Özet
Adsorptive removal of residual pharmaceuticals from wastewater has become an important issue from an environmental aspect. Macroporous polymer-based monoliths are being used as efficient adsorbents to remove such toxic materials. Regarding this, the ease of preparation, sustainability and low production cost are the most demanded properties from polymer-based monoliths. This work describes the synthesis of the first sustainable β-myrcene (My) and d-limonene (Lim) derived adsorbents by free radical copolymerization crosslinking in water-in-oil (w/o) high internal phase emulsions (HIPEs). To demonstrate the influence of purification and drying steps on the pore morphology of the monoliths, the samples were either vacuum dried (PMLE-E) or freeze-dried (PMLE-L). Characterization tests indicated that the specific surface area of the PMLE-E monolith (64.71 m2/g) was much higher than that of PMLE-L …
Anahtar Kelimeler
Adsorption | Emulsion templating | Ibuprofen | Limonene | Myrcene | Tetracycline