Influence of titania on the morphological and mechanical properties of 1,3-butanediol dimethacrylate based polyHIPE composites.
   
Yazarlar (5)
Fatma Nur Parın Bursa Teknik Üniversitesi, Türkiye
Doç. Dr. Hatice Hande MERT Yalova Üniversitesi, Türkiye
Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı REACTIVE & FUNCTIONAL POLYMERS (Q1)
Dergi ISSN 1381-5148 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2018
Cilt / Sayı / Sayfa 130 / 0 / 8–15 DOI 10.1016/j.reactfunctpolym.2018.05.009.
Makale Linki https://www.sciencedirect.com/science/article/pii/S1381514818301305
Özet
Macroporous polymer/TiO2 composites were synthesized by the polymerisation of 1,3-butanediol dimethacrylate (1,3-BDDMA) based water-in-oil high internal phase emulsions. High internal phase emulsions (HIPEs) having 80 vol% of internal phase were used as templates for inducing porosity in the resulting polymer composites. Apart from the monomer, either methyl methacrylate (MMA) or 2-ethylhexyl acrylate (EHA) was used as a co-monomer. In order to investigate the influence of nanoparticle loading on the morphological and mechanical properties of highly porous polymers, 1 to 10 wt% of colloidal TiO2 nanoparticles were introduced into emulsion templates. It was found that increasing the amount of nanoparticle loading from 1 wt% to 10 wt%, average cavity sizes decreased from 14.1 μm to 5.9 μm in the case of MMA co-monomer, and from 18.6 μm to 5.1 μm in the case of EHA co-monomer …
Anahtar Kelimeler
polyHIPE | Titania | Nanocomposites | Porous polymers | Regression analysis