Influence of nanoparticles and antioxidants on mechanical properties of titania/polydicyclopentadiene polyHIPEs: A statistical approach

Yüce, E.; Krajnc, P.; MERT, Hatice Hande; MERT, Emine Hilal

doi:10.1002/app.46913

Influence of nanoparticles and antioxidants on mechanical properties of titania/polydicyclopentadiene polyHIPEs: A statistical approach

Yazarlar (4)

E. Yüce Yalova Üniversitesi, Türkiye

P. Krajnc Univerza V Mariboru, Slovenya

Doç. Dr. Hatice Hande MERT Yalova Üniversitesi, Türkiye

Prof. Dr. Emine Hilal MERT Yalova Üniversitesi, Türkiye

Makale Türü	Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı	Journal of Applied Polymer Science
Dergi ISSN	0021-8995 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler	SCI-Expanded
Makale Dili	İngilizce	Basım Tarihi	02-2019
Cilt / Sayı / Sayfa	136 / 7 / –	DOI	10.1002/app.46913
Makale Linki	http://doi.wiley.com/10.1002/app.46913

Özet

Open porous Pickering poly(high internal phase emulsion) composites were prepared by ring opening metathesis polymerization of surface modified TiO2 nanoparticle stabilized dicyclopentadiene (DCPD) high internal phase emulsions. Oxidation of the double bonds in the polyDCPD chains of the resulting materials was prevented using antioxidants. Oxidation dependent variation of mechanical properties was demonstrated by applying compression tests to the resulting composite materials periodically. Periodical measurements revealed significantly reduced brittleness in the case of antioxidant containing polyHIPE composites. Furthermore, it was determined that the initial compression moduli and the compressive strengths of the resulting materials were significantly improved by using antioxidants as compared to antioxidant free samples. Moreover, increasing nanoparticle amount was found to have a beneficial effect with the presence of antioxidants. The relationship between the compression modulus with nanoparticle loading and different types of antioxidants was revealed by developing model regression equations and graphs. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 46913.

Anahtar Kelimeler

dicyclopentadiene | mechanical properties | nanocomposite | polyHIPE | porous polymers

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
WoS	22
SCOPUS	24
Google Scholar	25

Influence of nanoparticles and antioxidants on mechanical properties of titania/polydicyclopentadiene polyHIPEs: A statistical approach

Dergi Adı	JOURNAL OF APPLIED POLYMER SCIENCE
Yayıncı	John Wiley & Sons Inc.
Açık Erişim	Hayır
ISSN	0021-8995
E-ISSN	1097-4628
CiteScore	5,8
SJR	0,572
SNIP	0,700

Influence of nanoparticles and antioxidants on mechanical properties of titania/polydicyclopentadiene polyHIPEs: A statistical approach

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