Quantifying Structural and Solid State Viscoelastic Properties of Poly propylene PP Poly oxymethylene POM Blend Films
   
Yazarlar (3)
Doç. Dr. Alper KAŞGÖZ Yalova Üniversitesi, Türkiye
Dincer Akin Istanbul Üniversitesi, Türkiye
Ali Durmuş İstanbul Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Macromolecular Materials and Engineering
Dergi ISSN 1438-7492 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 11-2016
Cilt / Sayı / Sayfa 301 / 11 / 1402–1414 DOI 10.1002/mame.201600109
Makale Linki http://doi.wiley.com/10.1002/mame.201600109
Özet
In this study, isotactic poly(propylene) (PP)/poly(oxymethylene) (POM) blend films, including of POM as minor phase in the range of 10–30 wt%, are prepared in a twin screw extruder equipped with a slit-die and cast film haul-off unit. It is found that the blend films show characteristic immiscible matrix-droplet morphology. Short-term uniaxial tensile creep behaviors of films imply that the introducing of POM significantly improves the elastic modulus and decreases the total creep strain of PP/POM blends. Creep tests are also performed at various temperatures and long-term deformations of samples are predicted by applying of time-temperature superposition principle and the Findley model. It is found that the presence of POM domains into PP matrix enhances the creep resistance of PP especially at high temperatures. It is concluded that the PP-rich PP/POM blend films show much lower short and long-term creep strains compared to PP. (Figure presented.).
Anahtar Kelimeler
creep | dynamic mechanic analysis (DMA) | poly(oxymethylene) (POM) | poly(propylene) (PP) | viscoelasticity