From Single-Chain Polymeric Nanoparticles to Interpenetrating Polymer Network Organogels: A One-Pot Fabrication Approach
Yazarlar (4)
Selin Dağlar
Prof. Dr. Demet Karaca Balta Yıldız Teknik Üniversitesi, Türkiye
Prof. Dr. Binnur Temel Bezm-İ Âlem Vakıf Üniversitesi, Türkiye
Prof. Dr. İsmail Gökhan TEMEL Yalova Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Gels (Q1)
Dergi ISSN 2310-2861 Dergi Bilgileri (2025)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 02-2025
Kabul Tarihi Yayınlanma Tarihi 07-02-2025
Cilt / Sayı / Sayfa 11 / 2 / – DOI 10.3390/gels11020122
Makale Linki https://doi.org/10.3390/gels11020122
UAK Araştırma Alanları
Polimer Bilimi
Özet
In this study, we developed a novel one-pot synthesis method to fabricate well-defined single-chain polymeric nanoparticles (SCNPs) integrated with interpenetrating polymer network (IPN) systems. The synthesis process involved an initial intramolecular crosslinking of poly(methyl methacrylate-co-glycidyl methacrylate) to form SCNP followed by intermolecular crosslinking to produce single-chain nanogel (SCNG) structures. In addition, the achieved single-chain polymeric nanoparticle was subsequently incorporated into an IPN structure through urethane bond formation and a Diels–Alder click reaction involving furfuryl methacrylate (FMA) and bismaleimide (BMI). The thermal properties, swelling behaviors, and morphologies of the resulting SCNP-IPN systems were investigated. This work presents a novel strategy that integrates the single-chain folding concept with IPN systems, providing a promising platform for the development of robust and functional polymeric materials with potential applications in advanced materials science.
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