Preparation of poly(oxanorbornene) based single and double-folding polymers via nucleophilic aromatic substitution reaction
Yazarlar (4)
Öğr. Gör. Dr. Burcu ALKAN
Yalova Üniversitesi, Türkiye
Binnur Temel
Bezm-İ Âlem Vakıf Üniversitesi, Türkiye
Hakan Durmaz
İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. İsmail Gökhan TEMEL
Yalova Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | European Polymer Journal (Q1) | ||
| Dergi ISSN | 0014-3057 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 01-2024 |
| Cilt / Sayı / Sayfa | 203 / 0 / 112694– | DOI | 10.1016/j.eurpolymj.2023.112694 |
| Makale Linki | http://dx.doi.org/10.1016/j.eurpolymj.2023.112694 | ||
| Özet |
| A facile approach is introduced to prepare single-chain nanoparticles (SCNPs) utilizing intramolecular crosslinking based on nucleophilic aromatic substitution reaction. The linear polymeric precursor comprising dichlorotriazine (DCT) moiety as a reactive pendant group is synthesized via ring-opening metathesis polymerization (ROMP). The reactive chlorine atoms on DCT motifs are substituted with a dithiol nucleophile in varying degrees to yield individually intramolecularly crosslinked polymer nanoparticles. In addition, double-collapse and modification reactions are exploited through the substitution reaction from the remaining unreacted chlorine atoms. A significant reduction in hydrodynamic volumes of the corresponding SCNPs is observed compared to their linear analogues. The obtained nanoparticles are characterized by size exclusion chromatography (SEC), proton nuclear magnetic resonance … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 9 |