Synthesis and characterization of POSS hybrid organogels using Menschutkin quaternization chemistry
Yazarlar (4)
Deniz Kılıç
Yıldız Teknik Üniversitesi, Türkiye
Demet Karaca Balta
Yıldız Teknik Üniversitesi, Türkiye
Didem Saloğlu Dertli
Yalova Üniversitesi, Türkiye
Prof. Dr. İsmail Gökhan TEMEL
Yalova Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | POLYMER INTERNATIONAL | ||
| Dergi ISSN | 0959-8103 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 03-2019 |
| Cilt / Sayı / Sayfa | 68 / 3 / 369–376 | DOI | 10.1002/pi.5719 |
| Özet |
| The present research describes a series of organic–inorganic hybrid gels based on polystyrene and polyhedral oligomeric silsesquioxanes (POSSs) prepared using free radical copolymerization and Menschutkin chemistry techniques. In the first step, poly(styrene‐co‐chloromethylstyrene) is readily achieved by thermally initiated radical copolymerization and the subsequently obtained copolymer reacts with diethanolamine functional POSS nanoparticles which are employed as the crosslinker. The resulting hybrid network possesses ionic moieties and inorganic POSS nanoparticles. The POSS‐containing hybrid gels exhibit excellent organic solvent absorption and show good mechanical behaviour. Gel containing 0.8 × 10−3 mmol of POSS(DEA)8 (DEA, diethanolamine) reached the highest swelling ratio; hence, the corresponding gel can absorb organic solvent up to 20× its weight. The rate constant, coefficients … |
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BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 8 |