Preparation of water dispersible carbon nanotubes using photoinduced hyperbranched copolymerization and noncovalent interactions
   
Yazarlar (2)
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı EUROPEAN POLYMER JOURNAL
Dergi ISSN 0014-3057 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 08-2018
Cilt / Sayı / Sayfa 105 / 0 / 398–404 DOI 10.1016/j.eurpolymj.2018.06.007
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0014305718300041
Özet
Amine containing methacrylic based hyperbranched copolymers were prepared according to type II photoinitiation methodology in the presence of a commercially available photoinitiator. Several feed ratios of 2-(diethylamino)ethyl methacrylate and methyl methacrylate monomers were used to obtain copolymers with varying branching densities. Resulting copolymers were easily modified using pyrene functional compound via Menschutkin quaternization reaction. Subsequently, pyrene possessing hyperbranched copolymers were attached onto multiwalled carbon nanotube surface by π-π stacking strategy. Gel permeation chromatography, thermal gravimetric analysis and UV spectroscopy were utilized to analyze structures and molecular weight values of modified copolymers and precursors. Dispersion experiments of resulting copolymers/CNT were also carried out in organic and aqueous media in different pH …
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