Photopolymerization of acrylamide with benzophenone methylated cyclodextrin inclusion complex in the presence of jeffamine based dendrimers as coinitiators in aqueous media
   
Yazarlar (4)
Prof. Dr. İsmail Gökhan TEMEL Yalova Üniversitesi, Türkiye
Tezcan Paralı Çanakkale Onsekiz Mart Üniversitesi, Türkiye
Nergis Arsu Yıldız Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Photochemistry and Photobiology A: Chemistry
Dergi ISSN 1010-6030 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 06-2010
Cilt / Sayı / Sayfa 213 / 1 / 46–51 DOI 10.1016/j.jphotochem.2010.04.018
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S1010603010001498
Özet
BP/Me-β-CD inclusion complex was synthesized and used in photoinduced free radical polymerization of acrylamide as a type II photoinitiator in the presence of a dendritic co-initiator. Characterization and photophysical studies of the inclusion complex were determined by 1H NMR, UV, laser flash photolysis and phosphorescence spectroscopy. According to acrylamide polymerization of the BP/Me-β-CD water soluble photoinitiator, BP/Me-β-CD initiates polymerization of acrylamide effectively with six and twelve armed dendritic co-initiators in aqueous media. The 24 armed dendritic co-initiator was not as efficient as the six and twelve armed dendritic co-initiators with the BP/Me-β-CD inclusion complex, due to the sterical hindrance of the amine groups in the co-initiator.
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